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Monitoring and Controlling Chemical Reactions

Surface area and rate

  • 3 things to know
  • Paper 10 (Chemistry)

Overview

How breaking a solid up raises its surface area to volume ratio, why powders react faster, the cube calculations, the flour dust hazard, and comparing the graphs for powder and lumps.

What you need to know

Answer each one before you reveal it.

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Key term

Explain why a powdered solid reacts faster than the same mass of the solid in one large lump.

Key term

Which particles of a solid reactant are able to take part in a reaction with a solution?

Numbers

A cube of solid has sides of 3 cm. Calculate its surface area, its volume and its surface area to volume ratio.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What happens to the surface area to volume ratio of a solid when it is broken into smaller pieces?

    Model answer

    It increases, because cutting the solid creates new surfaces while the total volume stays the same.

  2. 2

    Explain why a powdered solid reacts faster than the same mass of the solid in one large lump.

    Model answer

    The powder has a much larger surface area to volume ratio, so many more of its particles are exposed and collisions with the other reactant are more frequent.

  3. 3

    Which particles of a solid reactant are able to take part in a reaction with a solution?

    Model answer

    Only the particles on the surface, because the ones inside cannot be reached by the solution.

  4. 4

    A cube of solid has sides of 3 cm. Calculate its surface area, its volume and its surface area to volume ratio.

    Model answer

    The surface area is 6 × 3 × 3 = 54 cm², the volume is 27 cm³, and the ratio is 54:27, which is 2:1.

  5. 5

    A cube of side 3 cm is cut into twenty-seven cubes of side 1 cm. Calculate the new total surface area and the new surface area to volume ratio.

    Model answer

    Each small cube has a surface area of 6 cm², so the total is 162 cm² for the same 27 cm³, giving a ratio of 6:1, three times the original.

  6. 6

    A solid is ground until its pieces are one tenth of their original size in every direction. What happens to the surface area to volume ratio?

    Model answer

    It becomes ten times greater, because the ratio for a cube is inversely proportional to the length of its side.

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