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Extracting Metals and Equilibria

Changing the position of an equilibrium

  • 3 things to know
  • Paper 3

Overview

How temperature, pressure, reactant concentration and removing a product shift the position of an equilibrium, applied to predicting the effects on N₂ + 3H₂ ⇌ 2NH₃, H₂ + I₂ ⇌ 2HI and the colour of N₂O₄ ⇌ 2NO₂.

What you need to know

Answer each one before you reveal it.

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Key term

How does raising the temperature affect the position of a dynamic equilibrium?

Key term

How does lowering the temperature affect the position of a dynamic equilibrium?

Key term

How does raising the pressure affect the position of an equilibrium involving gases?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    How does raising the temperature affect the position of a dynamic equilibrium?

    Model answer

    The equilibrium shifts in the direction of the endothermic reaction.

  2. 2

    How does lowering the temperature affect the position of a dynamic equilibrium?

    Model answer

    The equilibrium shifts in the direction of the exothermic reaction.

  3. 3

    How does raising the pressure affect the position of an equilibrium involving gases?

    Model answer

    The equilibrium shifts towards the side with the smaller number of gas molecules.

  4. 4

    In the equilibrium N₂ + 3H₂ ⇌ 2NH₃, which side is favoured by an increase in pressure, and why?

    Model answer

    The ammonia side is favoured, because four molecules of gas on the left become only two on the right.

  5. 5

    How does increasing the concentration of a reactant affect the position of an equilibrium?

    Model answer

    The equilibrium shifts towards the products in order to use up the extra reactant.

  6. 6

    How does continually removing a product affect the position of an equilibrium?

    Model answer

    The equilibrium shifts towards the products in order to replace what has been taken away.

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Key Concepts in Chemistry
States of Matter and Mixtures
Chemical Changes
Extracting Metals and Equilibria

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Hydrogen is formed.
chloridebromideiodide

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AChlorine is a pale green gas at room temperature.
BBromine is a red-brown liquid at room temperature.
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A neutral solution has a pH of 7.
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