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Monitoring and Controlling Chemical Reactions

Factors affecting rate, and collision theory

  • 3 things to know
  • Paper 2

Overview

How temperature, concentration, pressure and surface area affect rate, why concentration changes the speed but not the amount of product, the rough doubling for each 10 °C rise, how rate changes during a reaction, the two conditions for a successful collision, explaining each factor with collision theory and activation energy, reading rate ∝ 1/t, and planning, evaluating and improving the sodium thiosulfate investigation.

What you need to know

Answer each one before you reveal it.

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Key term

Describe the effect of raising the temperature on the rate of a reaction.

Key term

Describe the effect of increasing the concentration of a reactant in solution on the rate of a reaction.

Key term

Describe the effect of increasing the pressure on a reaction between gases.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    Describe the effect of raising the temperature on the rate of a reaction.

    Model answer

    The rate increases, so the reaction finishes sooner.

  2. 2

    Describe the effect of increasing the concentration of a reactant in solution on the rate of a reaction.

    Model answer

    The rate increases, and the graph of product against time becomes steeper at the start.

  3. 3

    Describe the effect of increasing the pressure on a reaction between gases.

    Model answer

    The rate increases.

  4. 4

    Describe what happens to the rate when a solid reactant is ground into a powder instead of being used as one lump.

    Model answer

    The rate increases because the surface area of the solid is much greater.

  5. 5

    If the same amounts of reactants are used, does increasing the concentration change the total mass of product formed?

    Model answer

    No, only the speed at which it is formed changes; the final amount of product is the same.

  6. 6

    Roughly what happens to the rate of many reactions when the temperature is raised by 10 °C?

    Model answer

    The rate roughly doubles.

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Chemical Reactions
Elements, Compounds and Mixtures
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Monitoring and Controlling Chemical Reactions

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Values 7.
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AThe products sit at a higher energy level than the reactants.
BThe activation energy, the energy that must be supplied before the reaction can happen.
CThe reactants, the products, the activation energy and the overall energy change.

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Sodium ions give a bright yellow flame colour.
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