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Chemical Analysis, Organic Chemistry and Materials

What a polymer is, and how poly(ethene) forms

  • 2 things to know
  • Paper 2

Overview

What polymers, monomers and repeating units are and why a polymer's relative molecular mass is an average, and how ethene's double bond opens in addition polymerisation to form poly(ethene) with the repeating unit –CH₂–CH₂–.

What you need to know

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Key term

What is a polymer?

Key term

Why is the relative molecular mass of a polymer described as an average rather than a fixed value?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What is a polymer?

    Model answer

    A polymer is a substance with a high average relative molecular mass made from many small repeating units joined together.

  2. 2

    What name is given to the small molecules that join together to make a polymer?

    Model answer

    They are called monomers.

  3. 3

    Why is the relative molecular mass of a polymer described as an average rather than a fixed value?

    Model answer

    Different polymer molecules in the same sample contain different numbers of repeating units, so their masses vary.

  4. 4

    How does the relative molecular mass of a polymer molecule compare with that of the monomer it was made from?

    Model answer

    The polymer molecule has a far higher relative molecular mass because it contains many monomer units joined together.

  5. 5

    What is meant by the repeating unit of a polymer?

    Model answer

    It is the small group of atoms that occurs over and over again along the polymer chain.

  6. 6

    How can a polymer molecule containing thousands of atoms be represented simply?

    Model answer

    It can be shown by its repeating unit, since the same unit is repeated along the whole chain.

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