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Quantitative Chemistry

Atom economy

  • 3 things to know
  • Paper 1

Overview

What atom economy measures and why a high value matters for sustainability and cost, the information and equation needed to calculate it, why a single-product reaction scores 100%, worked calculations for calcium oxide, iron and zinc oxide, and weighing atom economy against yield, rate, equilibrium and by-products when choosing a pathway.

What you need to know

Answer each one before you reveal it.

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Key term

Explain why using reactions with a high atom economy matters for sustainable development.

Key term

Give an economic reason for choosing a reaction with a high atom economy.

Key term

What information is needed before the atom economy of a reaction can be calculated?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What does the atom economy of a reaction measure?

    Model answer

    It measures how much of the starting materials ends up as the useful product.

  2. 2

    Give another name for atom economy.

    Model answer

    Atom utilisation.

  3. 3

    Explain why using reactions with a high atom economy matters for sustainable development.

    Model answer

    Less of the raw material is turned into waste, so limited resources last longer and there is less waste to dispose of.

  4. 4

    Give an economic reason for choosing a reaction with a high atom economy.

    Model answer

    Less raw material is wasted for each tonne of product, and less money is spent separating and disposing of unwanted by-products.

  5. 5

    What information is needed before the atom economy of a reaction can be calculated?

    Model answer

    The balanced equation, and the relative formula masses of the desired product and of all the reactants.

  6. 6

    State the equation used to calculate percentage atom economy.

    Model answer

    Percentage atom economy = relative formula mass of the desired product ÷ sum of the relative formula masses of all the reactants × 100.

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