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The Rate and Extent of Chemical Change

The effect of temperature changes on equilibrium

  • 3 things to know
  • Paper 2

Overview

Why raising the temperature shifts an equilibrium in the endothermic direction and lowering it in the exothermic direction, the effect on yield for each type of forward reaction, ammonia and N₂O₄ as examples, and the compromise industrial temperature.

What you need to know

Answer each one before you reveal it.

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Key term

Explain why raising the temperature of a mixture at equilibrium disturbs it.

Key term

The forward reaction of a reversible reaction is endothermic. State the effect of raising the temperature on the relative amount of products at equilibrium.

Key term

The forward reaction of a reversible reaction is exothermic. State the effect of raising the temperature on the relative amount of products at equilibrium.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    State the direction in which the position of equilibrium moves when the temperature of an equilibrium mixture is raised.

    Model answer

    It moves in the endothermic direction, because that direction takes in energy and so opposes the rise in temperature.

  2. 2

    Explain why raising the temperature of a mixture at equilibrium disturbs it.

    Model answer

    The forward and reverse reactions are no longer at the same rate, and the system shifts in the direction that absorbs energy until equilibrium is restored.

  3. 3

    The forward reaction of a reversible reaction is endothermic. State the effect of raising the temperature on the relative amount of products at equilibrium.

    Model answer

    The relative amount of products increases.

  4. 4

    The forward reaction of a reversible reaction is exothermic. State the effect of raising the temperature on the relative amount of products at equilibrium.

    Model answer

    The relative amount of products decreases.

  5. 5

    The formation of ammonia from nitrogen and hydrogen is exothermic. Predict the effect of raising the temperature on the amount of ammonia in the equilibrium mixture.

    Model answer

    The amount of ammonia falls, because the equilibrium shifts back towards nitrogen and hydrogen.

  6. 6

    State the direction in which the position of equilibrium moves when the temperature of an equilibrium mixture is lowered.

    Model answer

    It moves in the exothermic direction, because that direction releases energy and so opposes the fall in temperature.

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