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The Rate and Extent of Chemical Change

The effect of changing conditions on equilibrium

  • 3 things to know
  • Paper 2

Overview

How conditions fix the relative amounts at equilibrium, how a system counteracts a change, Le Chatelier's Principle, what a position lying to the right means, and the ammonia equilibrium under changes of temperature, pressure and concentration.

What you need to know

Answer each one before you reveal it.

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Key term

State what decides the relative amounts of reactants and products present in a mixture at equilibrium.

Key term

State how a system at equilibrium responds when one of the conditions is changed.

Key term

Explain what counteracting the change means when the concentration of a reactant in an equilibrium mixture is increased.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    State what decides the relative amounts of reactants and products present in a mixture at equilibrium.

    Model answer

    The conditions of the reaction, such as the temperature, the pressure and the concentrations used.

  2. 2

    The same reversible reaction is allowed to reach equilibrium at two different temperatures. State whether the proportions of reactants and products will be the same in each case.

    Model answer

    No, the relative amounts depend on the conditions, so the two equilibrium mixtures will differ.

  3. 3

    State how a system at equilibrium responds when one of the conditions is changed.

    Model answer

    The system responds in the direction that counteracts, or opposes, the change that was made.

  4. 4

    Explain what counteracting the change means when the concentration of a reactant in an equilibrium mixture is increased.

    Model answer

    The system reacts to remove some of the added reactant, so the position of equilibrium moves towards the products.

  5. 5

    State whether an equilibrium mixture returns to exactly its original composition after a condition has been changed.

    Model answer

    No, it settles at a new equilibrium in which the relative amounts of reactants and products are different.

  6. 6

    Name the principle used to predict the effect of a change in conditions on a system at equilibrium.

    Model answer

    Le Chatelier's Principle.

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