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Groups in the Periodic Table

Displacement reactions of the halogens

  • 3 things to know
  • Paper 4

Overview

The rule for halogen displacement, the order chlorine, bromine, iodine, the colours seen with potassium bromide and potassium iodide solutions, the balanced equations, and predicting when no displacement happens, including for astatine.

What you need to know

Answer each one before you reveal it.

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Key term

State the rule that decides whether a halogen displaces a halide from solution.

Key term

Place chlorine, bromine and iodine in order of reactivity, starting with the most reactive.

Key term

What is seen when chlorine water is added to colourless potassium bromide solution?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    State the rule that decides whether a halogen displaces a halide from solution.

    Model answer

    A more reactive halogen displaces a less reactive halogen from a solution of its halide.

  2. 2

    Place chlorine, bromine and iodine in order of reactivity, starting with the most reactive.

    Model answer

    Chlorine is the most reactive, then bromine, and iodine is the least reactive.

  3. 3

    What is seen when chlorine water is added to colourless potassium bromide solution?

    Model answer

    The solution turns orange, because bromine has been displaced.

  4. 4

    What is seen when chlorine water is added to colourless potassium iodide solution?

    Model answer

    The solution turns brown, because iodine has been displaced.

  5. 5

    Write the balanced equation for chlorine reacting with potassium bromide solution.

    Model answer

    Cl₂ + 2KBr → 2KCl + Br₂.

  6. 6

    Write the balanced equation for bromine reacting with potassium iodide solution.

    Model answer

    Br₂ + 2KI → 2KBr + I₂.

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Hydrogen is formed.
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AChlorine is a pale green gas at room temperature.
BBromine is a red-brown liquid at room temperature.
CIodine is a dark grey solid at room temperature.

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