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Rates of Reaction and Energy Changes

Collision theory and factors affecting rate

  • 3 things to know
  • Paper 4

Overview

The conditions for a successful collision, collision frequency and energy, how temperature, concentration, surface area and pressure affect rate, why reactions slow as reactants are used up, and calculating surface area to volume ratios.

What you need to know

Answer each one before you reveal it.

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Key term

Use collision theory to explain why reactions slow as they proceed, why solids react slowly, and how temperature and surface area speed reactions.

Key term

Explain in terms of collisions how pressure, powdering a solid and cooling affect rate, and why pressure does not affect solutions.

Key term

State the two conditions that must be met for reactant particles to react.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    State the two conditions that must be met for reactant particles to react.

    Model answer

    The particles must collide with one another, and they must collide with enough energy.

  2. 2

    What name is given to the explanation that reactions happen when particles collide?

    Model answer

    Collision theory.

  3. 3

    State the two ways in which the rate of a reaction can be increased in terms of collisions.

    Model answer

    Either the frequency of collisions is increased, or the energy of the collisions is increased.

  4. 4

    What is meant by the frequency of collisions?

    Model answer

    It is the number of collisions that happen each second.

  5. 5

    Explain why not every collision between reactant particles causes a reaction.

    Model answer

    A collision only leads to a reaction if the colliding particles have at least the minimum energy needed.

  6. 6

    A reaction mixture gradually slows down as it is left. Explain this in terms of collisions.

    Model answer

    The reactants are being used up, so fewer particles remain and collisions become less frequent.

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Key Concepts in Chemistry
States of Matter and Mixtures
Chemical Changes
Extracting Metals and Equilibria

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Hydrogen is formed.
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