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The Rate and Extent of Chemical Change

Collision theory and activation energy

  • 3 things to know
  • Chemistry Paper 2

Overview

The two conditions for colliding particles to react and activation energy, what collision theory explains, why higher concentration, gas pressure, surface area and temperature make collisions more frequent or more energetic, surface area to volume ratio, predicting rate changes when conditions are altered, and the symbols for proportionality, much less than, much greater than and approximately.

What you need to know

Answer each one before you reveal it.

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Key term

State the two conditions that must be met when reacting particles meet if a reaction is to happen.

Key term

Explain why not every collision between reacting particles produces a reaction.

Key term

Explain, using collision theory, why increasing the pressure of reacting gases increases the rate of reaction.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    State the two conditions that must be met when reacting particles meet if a reaction is to happen.

    Model answer

    The particles must collide with each other, and the collision must have enough energy.

  2. 2

    Define the activation energy of a reaction.

    Model answer

    It is the minimum amount of energy that particles must have in order to react when they collide.

  3. 3

    State what collision theory is used to explain.

    Model answer

    It explains how factors such as concentration, pressure, surface area and temperature affect the rate of a reaction.

  4. 4

    Explain why not every collision between reacting particles produces a reaction.

    Model answer

    Many collisions have less energy than the activation energy, so the particles simply bounce apart without reacting.

  5. 5

    Explain, using collision theory, why increasing the concentration of a solution increases the rate of reaction.

    Model answer

    There are more reacting particles in the same volume of solution, so collisions between them are more frequent.

  6. 6

    Explain, using collision theory, why increasing the pressure of reacting gases increases the rate of reaction.

    Model answer

    The same number of gas particles is squeezed into a smaller volume, so the particles are closer together and collide more frequently.

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