AQA A-Level Chemistry 7405
Atomic Structure
Amount of Substance
Bonding
Energetics and Thermodynamics
Kinetics
Chemical Equilibria
Redox and Electrochemistry
Acids and Bases
Periodicity and Group Chemistry
Period 3 Elements and Their Oxides
Transition Metals
Introduction to Organic Chemistry
Hydrocarbons
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Carbonyls, Carboxylic Acids and Derivatives
Aromatic Chemistry and Amines
Polymers, Amino Acids, Proteins and DNA
Organic Synthesis, NMR and Chromatography
Transition Metals
Metal Aqua Ions with Bases: Reactions with Hydroxide and Ammonia
- 3 things to know
- Papers 1 and 3
Overview
Adding sodium hydroxide or ammonia to metal aqua ions, and the precipitates and colours that identify them.
What you need to know
Answer each one before you reveal it.
When sodium hydroxide is added to a solution containing [Fe(H₂O)₆]²⁺, what is the initial product formed?
What colour precipitate forms when sodium hydroxide is added to iron(II) aqua ions?
Questions from this subtopic
Each one with the model answer underneath.
- 1
What happens when a metal aqua ion reacts with a base such as sodium hydroxide or ammonia?
Model answer
The base deprotonates the aqua ion, removing H⁺ from coordinated water molecules to form a metal hydroxide precipitate
- 2
When sodium hydroxide is added to a solution containing [Fe(H₂O)₆]²⁺, what is the initial product formed?
Model answer
[Fe(H₂O)₄(OH)₂] or Fe(OH)₂ precipitate
- 3
When sodium hydroxide is added to a solution containing [Fe(H₂O)₆]³⁺, what is the initial product formed?
Model answer
[Fe(H₂O)₃(OH)₃] or Fe(OH)₃ precipitate
- 4
What colour precipitate forms when sodium hydroxide is added to iron(II) aqua ions?
Model answer
Green (which darkens on standing due to oxidation)
- 5
What colour precipitate forms when sodium hydroxide is added to iron(III) aqua ions?
Model answer
Rust brown/orange-brown
- 6
When sodium hydroxide is added to a solution containing [Cu(H₂O)₆]²⁺, what precipitate forms?
Model answer
[Cu(H₂O)₄(OH)₂] or Cu(OH)₂ precipitate
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