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Transition Metals

Metal Aqua Ions with Bases: Reactions with Hydroxide and Ammonia

  • 3 things to know
  • Papers 1 and 3

Overview

Adding sodium hydroxide or ammonia to metal aqua ions, and the precipitates and colours that identify them.

What you need to know

Answer each one before you reveal it.

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Key term

What happens when a metal aqua ion reacts with a base such as sodium hydroxide or ammonia?

Key term

When sodium hydroxide is added to a solution containing [Fe(H₂O)₆]²⁺, what is the initial product formed?

Key term

What colour precipitate forms when sodium hydroxide is added to iron(II) aqua ions?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What happens when a metal aqua ion reacts with a base such as sodium hydroxide or ammonia?

    Model answer

    The base deprotonates the aqua ion, removing H⁺ from coordinated water molecules to form a metal hydroxide precipitate

  2. 2

    When sodium hydroxide is added to a solution containing [Fe(H₂O)₆]²⁺, what is the initial product formed?

    Model answer

    [Fe(H₂O)₄(OH)₂] or Fe(OH)₂ precipitate

  3. 3

    When sodium hydroxide is added to a solution containing [Fe(H₂O)₆]³⁺, what is the initial product formed?

    Model answer

    [Fe(H₂O)₃(OH)₃] or Fe(OH)₃ precipitate

  4. 4

    What colour precipitate forms when sodium hydroxide is added to iron(II) aqua ions?

    Model answer

    Green (which darkens on standing due to oxidation)

  5. 5

    What colour precipitate forms when sodium hydroxide is added to iron(III) aqua ions?

    Model answer

    Rust brown/orange-brown

  6. 6

    When sodium hydroxide is added to a solution containing [Cu(H₂O)₆]²⁺, what precipitate forms?

    Model answer

    [Cu(H₂O)₄(OH)₂] or Cu(OH)₂ precipitate

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