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Physical Chemistry in Industrial Processes

  • 9 subtopics
  • 27 things to know
  • AS 3

What Physical Chemistry in Industrial Processes covers

Physical Chemistry in Industrial Processes is examined in Unit AS 3, Aspects of Physical Chemistry in Industrial Processes — examined, a core unit. It covers moles, reacting masses and percentage yield, titration types, indicators and standard solutions, titration calculations and molarity, enthalpy changes and calorimetry, Hess's law and average bond enthalpies, collision theory, rates and the Maxwell–Boltzmann distribution, catalysts, chemisorption and catalytic converters, reversible reactions, the Haber process and the Contact process and scale-up, costs and siting a chemical plant.

Where it is assessed

AS 3

Aspects of Physical Chemistry in Industrial Processes — a written examination, compulsory.

Check the CCEA specification ↗

The 9 subtopics

Each one has its own page. CCEA AS Life and Health Sciences students sit this topic in the first year.

What you need to know

Answer each one before you reveal it.

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Key term

What mass of calcium carbonate (Mr = 100.1) must be heated to make 14.0 tonnes of calcium oxide (Mr = 56.1)?

Key term

Describe how the pH changes as sodium hydroxide is added from a burette to hydrochloric acid.

Key term

How can the rate of reaction between marble chips and hydrochloric acid be followed with a balance?

Key term

What does the term molarity mean?

Key term

Why do chemical reactions usually involve a heat change?

Key term

State the principle of conservation of energy.

Key term

Define a catalyst.

Key term

What is a reversible reaction?

Process

What is a batch process?

Key term

What is the relative formula mass of a substance?

Key term

Why is a solid weighed by difference when a standard solution is made?

Numbers

How is a volume in cm³ converted to dm³ in a concentration calculation?

Key term

Contrast exothermic and endothermic reactions.

Key term

State Hess's law.

Key term

Define rate of reaction and give its usual unit.

Key term

How does a catalyst change the reaction profile of a reaction?

Key term

What is meant by dynamic equilibrium?

Process

What is a continuous process?

Numbers

Calculate the relative formula mass of sulfuric acid, H₂SO₄, using Ar values H = 1.0, S = 32.1 and O = 16.0.

Key term

What mass of anhydrous sodium carbonate (Mr = 106.0) is needed to make 250 cm³ of a 0.100 mol dm⁻³ standard solution?

Key term

Titres of 23.85 cm³ (rough), 23.40 cm³, 23.10 cm³ and 23.20 cm³ are recorded. Which should be used, and what is the mean titre?

Key term

Give one industrial example of an exothermic reaction and one of an endothermic reaction.

Key term

How does Hess's law follow from the conservation of energy?

Key term

Define activation energy.

Key term

What is a heterogeneous catalyst?

Process

State the equation and enthalpy change for the Haber process.

Process

Why are pharmaceuticals usually made by batch processes?

Take Physical Chemistry in Industrial Processes further

The same content, four other ways.

Commonly confused

Pairs that lose marks when they are blurred together.

  • Batch process vs Continuous process

    Batch process: a method of manufacture that loads a fixed quantity of reactants, reacts them and empties the vessel before starting again. Continuous process: a method of manufacture that feeds reactants in and removes products without stopping for long periods.

  • Heterogeneous catalyst vs Homogeneous catalyst

    Heterogeneous catalyst: a rate-increasing substance in a different phase from the reacting chemicals. Homogeneous catalyst: a rate-increasing substance in the same phase as the reacting chemicals.

  • Percentage yield vs Atom economy

    Percentage yield: the proportion of the theoretical maximum mass of product that is actually obtained. Atom economy: the proportion of the total mass of products formed that is the desired product.

Questions from this topic

Each one with the model answer underneath.

  1. 1

    What is the relative formula mass of a substance?

    Model answer

    The relative formula mass is the sum of the relative atomic masses of all the atoms in its formula. Relative formula mass has no units.

  2. 2

    Calculate the relative formula mass of sulfuric acid, H₂SO₄, using Ar values H = 1.0, S = 32.1 and O = 16.0.

    Model answer

    The relative formula mass of H₂SO₄ is 98.1. The working is (2 × 1.0) + 32.1 + (4 × 16.0) = 98.1.

  3. 3

    What is one mole of a substance?

    Model answer

    One mole is the amount of substance containing 6.02 × 10²³ particles, the Avogadro constant. A mole of a substance has a mass in grams equal to its relative formula mass.

  4. 4

    State the relationship between amount in moles, mass and molar mass.

    Model answer

    The amount in moles equals the mass in grams divided by the molar mass in g mol⁻¹. Mass equals moles multiplied by molar mass.

  5. 5

    A water-treatment chemist weighs out 5.30 g of anhydrous sodium carbonate, Na₂CO₃ (Mr = 106.0). How many moles is this?

    Model answer

    The sample contains 0.0500 mol of sodium carbonate. The working is 5.30 ÷ 106.0 = 0.0500 mol.

  6. 6

    Why must a symbol equation be balanced before it is used to calculate reacting quantities?

    Model answer

    A balanced equation gives the mole ratio in which substances react and form. An unbalanced equation gives the wrong ratio and so the wrong masses.

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One cubic equals 1000 cm³.
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AThe energy of all bonds broken is added up.
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CA negative answer shows an exothermic reaction.

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Acidosis means blood pH falling below 7.35.
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Physical Chemistry in Industrial Processes revision questions

Is Physical Chemistry in Industrial Processes examined at AS in CCEA Life and Health Sciences?
Yes. It sits in AS 3, which you take in the first year, so it is on the AS paper as well as counting towards the full A level.
What does Physical Chemistry in Industrial Processes cover in CCEA AS-Level Life and Health Sciences?
9 subtopics: moles, reacting masses and percentage yield, titration types, indicators and standard solutions, titration calculations and molarity, enthalpy changes and calorimetry, hess's law and average bond enthalpies, collision theory, rates and the maxwell–boltzmann distribution, catalysts, chemisorption and catalytic converters, reversible reactions, the haber process and the contact process and scale-up, costs and siting a chemical plant. Each one has its own page with questions and model answers.
How is Physical Chemistry in Industrial Processes organised?
By the CCEA 0008 specification, subtopic by subtopic, so it matches the order you are taught it in.

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