CCEA A-Level Life and Health Sciences 0008
Experimental Techniques
Human Body Systems
Physical Chemistry in Industrial Processes
Brain ScienceDouble Award
Material ScienceDouble Award
Medicine, Drugs and Clinical TrialsDouble Award
Scientific Method, Investigation, Analysis and Evaluation
Organic Chemistry
Medical PhysicsA2 option
Sound and LightA2 option
Genetics, Stem Cell Research and CloningA2 option
MicrobiologyDouble Award
Oral Health and DentistryDouble Award
Histology and PathologyDouble Award
Analytical Chemistry TechniquesDouble Award
Enabling TechnologyDouble Award
Physical Chemistry in Industrial Processes
Collision theory, rates and the Maxwell–Boltzmann distribution
- 3 things to know
- AS 3
Overview
Rate and activation energy, reaction profiles, successful collisions, the effects of concentration, pressure and temperature, the Maxwell–Boltzmann distribution, and following rates by mass and titration.
What you need to know
Answer each one before you reveal it.
Define rate of reaction and give its usual unit.
Define activation energy.
Questions from this subtopic
Each one with the model answer underneath.
- 1
Define rate of reaction and give its usual unit.
Model answer
Rate of reaction is the change in concentration of a reactant or product per unit time. The usual unit is mol dm⁻³ s⁻¹.
- 2
Define activation energy.
Model answer
Activation energy is the minimum energy colliding particles need for a reaction to occur. Particles that collide with less energy simply bounce apart.
- 3
Describe the reaction profile for an exothermic reaction.
Model answer
The products lie at a lower energy than the reactants, with a peak between them. The activation energy is the rise from reactants to the peak, and ΔH is the overall drop.
- 4
How does the reaction profile of an endothermic reaction differ from an exothermic one?
Model answer
The products lie at a higher energy than the reactants, so ΔH is positive. The activation energy is still measured from the reactants to the peak.
- 5
State the two conditions a collision must meet to be successful.
Model answer
The particles must collide with energy equal to or greater than the activation energy. The particles must also collide with the correct orientation.
- 6
Explain why increasing the concentration of a solution increases the rate of reaction.
Model answer
A higher concentration puts more particles in the same volume. Collisions become more frequent, so there are more successful collisions per second.
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