Numbers
OCR A-Level Chemistry H432
Foundations in Chemistry
Topic overviewAtomic structure, isotopes and counting sub-atomic particlesRelative isotopic, atomic, molecular and formula massPredicting ionic charges and the common ionsWriting formulae, balanced equations and ionic equationsThe mole, molar mass and the Avogadro constantEmpirical and molecular formulae, and hydrated saltsGas volumes, concentration and the ideal gas equationStoichiometry, percentage yield and atom economyApparatus, and why high atom economy mattersMathematical skills and measuring mass, volume and gasAcids, alkalis, dissociation and neutralisationPreparing a standard solutionCarrying out a titration and its calculationsPlanning an experiment: variables, apparatus and recording resultsPractical safety, heating and filtrationUncertainty, percentage error, precision and accuracyEvaluating results: anomalies, conclusions, limitations and improvementsAssigning oxidation numbersRoman numerals in names, and the chlorate and nitrate ionsOxidation, reduction and metals reacting with acidsRedox equations and identifying what is oxidisedShells, orbitals and sub-shellsThe order in which sub-shells fillWriting electron configurations for atoms and ions
Bonding and Structure
Topic overviewIonic bonding and the properties of ionic compoundsCovalent and coordinate bondingLone pairs, bonding pairs and average bond enthalpyElectron pair repulsion theory, linear and trigonal planar shapesTetrahedral, pyramidal and non-linear shapes and their bond anglesOctahedral shapes, ions, and drawing molecules in three dimensionsElectronegativity, polar bonds and polar moleculesPermanent and induced dipoles, and hydrogen bondingSimple molecular lattices and why they melt easilySolubility and conductivity of simple molecular compounds
Periodic Table and Energy
Topic overviewPeriodicity and the electron configurations of periods 2 and 3The blocks, and first and successive ionisation energiesMetallic and giant covalent structures and their propertiesGroup 2 reactions with oxygen, water and acidsIonisation energy down Group 2 and the alkalinity of the hydroxidesUses of Group 2 compounds in agriculture and medicineThe halogens: boiling points, London forces and reactivityHalogen displacement reactions and the colours seenDisproportionation and the chlorination of waterTesting for halide ions with silver nitrate and ammoniaTesting for carbonate, sulfate and halide ionsTesting for ammonium ions and the order of the testsConcentration, pressure and measuring reaction rateCatalysts and their industrial importanceThe Boltzmann distribution, temperature and catalysts
Enthalpy Changes
Topic overviewExothermic and endothermic reactions and enthalpy profilesStandard conditions and the standard enthalpy changesBond enthalpies, q = mcΔT and calorimetryCalculating enthalpy change from bond enthalpiesWhy average bond enthalpies give only an approximationHess' law and enthalpy cycles from combustion and formation dataWorking through an enthalpy cycle and the sign conventionsCalorimetry and correcting for heat loss
Chemical Equilibrium
Basic Concepts of Organic Chemistry
Topic overviewIUPAC nomenclature and the alkyl groupsGeneral, structural, displayed and skeletal formulaeHomologous series, functional groups and saturationStructural isomers, bond fission and curly arrowsChain, position and functional group isomerismCurly arrows, homolytic and heterolytic fissionNucleophiles, electrophiles, radicals and the mechanism steps
Core Organic Chemistry
Topic overviewAlkanes: bonding, shape and boiling pointsCombustion of alkanes and their reaction with halogensThe radical substitution mechanism and its limitationsAlcohols: polarity, solubility and classificationOxidation, dehydration and substitution reactions of alcoholsHydrolysis of haloalkanes and comparing the ratesNucleophilic substitution and carbon-halogen bond strengthCFCs, radicals and the catalytic destruction of ozoneCombining analytical techniques to identify a compound
Alkenes
Topic overviewAlkenes: the double bond, sigma and pi bonding, and shapeE/Z and cis-trans isomerism in alkenesHydrogenation, halogenation and hydration of alkenesElectrophilic addition, carbocation stability and Markownikoff's ruleAddition polymerisation and repeat unitsWaste polymers, and biodegradable and photodegradable alternatives
Organic Synthesis
How Fast?
Topic overviewRate equations, order and the rate constantDeducing orders and finding the units of kWhat the rate equation reveals about the mechanismConcentration-time graphs and continuous monitoringHalf-life and the rate constant of a first-order reactionRate-concentration graphs and the initial rates methodClock reactions, colorimetry and analysing kinetic graphsThe rate-determining step and testing a proposed mechanismTemperature, the rate constant and the Arrhenius equationThe ln k against 1/T graph and finding the activation energy
Physical Chemistry and Transition Elements
Topic overviewMole fraction, partial pressure and ICE tablesKc and Kp expressions, their units and calculationsWhat changes the equilibrium constant, and the reaction quotientLattice enthalpy and the Born-Haber cycleEnthalpy of solution and hydration, and the effect of ionic charge and sizeEntropy and calculating entropy changeGibbs free energy and thermodynamic feasibility
Acids, Bases and Buffers
Topic overviewBrønsted-Lowry acids and bases and their reactionsKa, pKa, pH and the ionic product of waterCalculating the pH of strong acids, strong bases and weak acidspH and hydrogen ion concentrationWhat a buffer is and how it resists a change in pHBuffer calculations and the buffer that controls blood pHTitration curves, choosing an indicator and using a pH meterpH titration curves for the four acid-base combinationsHow an indicator works and choosing the right one
Redox and Electrode Potentials
Topic overviewOxidising and reducing agents, and balancing half-equationsCombining half-equations and using oxidation numbersRedox titrations and their calculationsStandard electrode potentials and setting up half-cellsThe electrochemical series and predicting feasibilityStorage cells and fuel cells
Transition Elements
Topic overviewLigands, complex ions and coordination numberElectron configurations from Sc to Zn, and which are transition elementsVariable oxidation states, coloured ions and catalysisThe shapes of complexes, stereoisomerism and cisplatinLigand substitution, haemoglobin and the copper complexesHydroxide precipitates of iron, manganese and chromiumRedox interconversions of iron, chromium and copperWhy ligand substitution happens and the changes it causesPrecipitation reactions written as aqua complexesDissolving hydroxides in excess ammonia and distinguishing the ions
Aromatic Compounds
Topic overviewThe delocalised model of benzene and the evidence for itNitration, halogenation and Friedel-Crafts reactions of benzeneThe reactions of phenol, and directing effectsElectrophilic substitution and directing effectsPhenol: acidity, bromination and nitrationWhy phenol is more reactive than benzene, and planning a synthesis
Organic Chemistry and Analysis
Topic overviewOxidation and reduction of carbonyls, and the addition of HCNThe nucleophilic addition mechanism2,4-DNPH and Tollens' reagentCarboxylic acids: solubility and reactions with metals, carbonates and basesEsterification and the hydrolysis of estersAcyl chlorides and their reactions with alcohols, amines and ammoniaAmines as bases, and preparing aliphatic aminesSecondary and tertiary amines, and preparing aromatic aminesAmino acids, their reactions, and amidesOptical isomerism and identifying a chiral centreCondensation polymerisation and the ester and amide linkagesHydrolysing condensation polymers and telling them from addition polymersNitriles from haloalkanes and from carbonyl compoundsFriedel-Crafts reactions and lengthening the carbon chainThin-layer and gas chromatography, Rf values and retention timesTest-tube tests for the organic functional groupsTests for the inorganic ions and interpreting chromatograms
Spectroscopy
Topic overviewCarbon-13 and proton NMR: peaks, chemical shift and integrationSpin-spin splitting and predicting a spectrumTMS, deuterated solvents and the D₂O shakeCombining elemental analysis, mass spectrometry, IR and NMRMolecular formula from the molecular ion, and fragmentation lossesWhat IR and NMR each contribute to a structureInfrared absorption, global warming and breathalysersA systematic approach and the degree of unsaturation
Chemical Equilibrium
- 4 subtopics
- 8 things to know
- Components 01 and 03
What Chemical Equilibrium covers
Dynamic equilibrium and how it responds to a change: le Chatelier's principle, the compromise conditions industry actually uses, and the equilibrium constant Kc as a measure of how far a reaction goes.
Where it is assessed
Components 01 and 03
Periodic Table, Elements and Physical Chemistry, then the unified paper.
Check the OCR specification ↗The 4 subtopics
Each one has its own page.
- Dynamic equilibrium and le Chatelier's principleRecall questions on the two conditions for dynamic equilibrium, why a closed system is needed, and the statement of le Chatelier's principle applied to concentration and temperature.Open →
- Pressure, catalysts and investigating a shift in equilibriumRecall questions on the effect of pressure in a gaseous system, why a catalyst does not move the position, and how a shift can be investigated experimentally.Open →
- Industrial compromise and the Haber processRecall questions on why yield, rate, safety and cost pull against each other, and on the temperature, pressure and catalyst chosen for the Haber process.Open →
- The equilibrium constant, KcRecall questions on where products and reactants sit in the Kc expression, and what a value much greater than, close to, or much less than 1 tells you.Open →
What you need to know
Answer each one before you reveal it.
Your recallNot started
Process
Which way does an equilibrium shift when the temperature is raised, when the temperature of an exothermic reaction is lowered, and when the pressure is increased?
Numbers
What does lowering the pressure do to a gaseous equilibrium, what does changing the pressure do to H₂(g) + I₂(g) ⇌ 2HI(g), and how does a catalyst affect the forward and reverse rates?
Numbers
What does a catalyst do to the time taken to reach equilibrium, and how can the effects of concentration and of temperature on equilibrium position be investigated?
Numbers
How does equilibrium yield influence the choice of industrial conditions?
Key term
What is the role of the iron catalyst in the Haber process?
Numbers
How are the concentrations of each species treated in the Kc expression with respect to the balanced equation?
Key term
What can you deduce about the composition of an equilibrium mixture when Kc is approximately equal to 1?
Take Chemical Equilibrium further
The same content, four other ways.
Commonly confused
Pairs that lose marks when they are blurred together.
Dynamic equilibrium vs Static equilibrium
Dynamic equilibrium: forward and reverse reactions continuing at equal rates in a closed system. Static equilibrium: a state with no continuing opposing reactions.
Equilibrium position vs Equilibrium constant
Equilibrium position: relative amounts of reactants and products at equilibrium. Equilibrium constant: a value calculated from equilibrium concentrations at a stated temperature.
Closed system vs Open system
Closed system: matter cannot enter or leave the reaction vessel. Open system: matter can enter or leave the reaction vessel.
Questions from this topic
Each one with the model answer underneath.
- 1
What two conditions must be met for a dynamic equilibrium to exist?
Model answer
The system must be closed, and the rate of the forward reaction must equal the rate of the reverse reaction.
- 2
At dynamic equilibrium, what happens to the concentrations of reactants and products over time?
Model answer
They remain constant over time.
- 3
Explain why the concentrations at dynamic equilibrium remain constant even though reactions are still occurring.
Model answer
The forward and reverse reactions occur at equal rates, so reactants are converted to products at the same rate as products are converted back to reactants.
- 4
Why must a system be closed for dynamic equilibrium to be established?
Model answer
No substances can enter or leave a closed system, so the reactants and products remain within the system to maintain equilibrium.
- 5
Does a reaction stop occurring once dynamic equilibrium is reached?
Model answer
No, both the forward and reverse reactions continue to occur simultaneously at equal rates.
- 6
State Le Chatelier's principle.
Model answer
When a system at equilibrium is subjected to a change, the position of equilibrium shifts to counteract that change.
What is inside Levo
Six ways to work the same material.
Chemical Equilibrium revision questions
- What does Chemical Equilibrium cover in OCR A-Level Chemistry?
- 4 subtopics: dynamic equilibrium and le chatelier's principle, pressure, catalysts and investigating a shift in equilibrium, industrial compromise and the haber process and the equilibrium constant, kc. Each one has its own page with questions and model answers.
- How is Chemical Equilibrium organised?
- By the OCR H432 specification, subtopic by subtopic, so it matches the order you are taught it in.
Every question in Chemical Equilibrium, on a schedule.
Attempt a question from memory, write the correct version, then attempt it again. Levo records the jump between your first attempt and your last, and brings each question back on the day you are due to forget it.
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