CCEA A-Level Environmental Technology 3930
Fossil Fuels
Global Action on Energy Conservation and Climate Change
Macrogeneration
Microgeneration
Energy From Wind
Energy From the Sun
Energy From Biomass
Energy Storage
Plastics for the Future
Renewable Energy Investigations
Sustainable Development
Waste Management
Waste to Energy Technologies
Land Contamination and Remediation
Hydrogen Fuel Cells
Transport System Challenges
Energy Performance of Buildings
Emerging Technologies
Sustainable Urban and Rural Communities
The Code for Sustainable Homes
Hydrogen Fuel Cells
Alkaline, phosphoric acid, molten carbonate and solid oxide fuel cells
- 3 things to know
- A2 1
Overview
The electrolyte, charge-carrying ion and half-equations of alkaline, phosphoric acid, molten carbonate and solid oxide cells, carbon dioxide poisoning, space use, stationary CHP, running on natural gas, and a comparison of the five types.
What you need to know
Answer each one before you reveal it.
Give the half-equations for an alkaline fuel cell.
Why is an alkaline fuel cell damaged by carbon dioxide?
Questions from this subtopic
Each one with the model answer underneath.
- 1
What electrolyte does an alkaline fuel cell use, and which ion carries the charge?
Model answer
An alkaline fuel cell uses potassium hydroxide solution as its electrolyte. Hydroxide ions, OH⁻, move through it from the cathode to the anode.
- 2
Give the half-equations for an alkaline fuel cell.
Model answer
The anode reaction is H₂ + 2OH⁻ → 2H₂O + 2e⁻. The cathode reaction is O₂ + 2H₂O + 4e⁻ → 4OH⁻.
- 3
Why is an alkaline fuel cell damaged by carbon dioxide?
Model answer
Carbon dioxide reacts with the hydroxide electrolyte to form potassium carbonate. The carbonate clogs the electrolyte and electrodes, so the cell needs pure oxygen or air scrubbed of carbon dioxide.
- 4
Where have alkaline fuel cells been used successfully?
Model answer
Alkaline fuel cells powered the Apollo spacecraft and the Space Shuttle. The cells supplied electricity, and the water they made was used by the crew.
- 5
What advantage does an alkaline fuel cell have over a PEM cell?
Model answer
The alkaline cell's electrode reactions are fast, so cheaper catalysts such as nickel can replace platinum. Alkaline cells can also reach high electrical efficiencies.
- 6
What is the electrolyte in a phosphoric acid fuel cell?
Model answer
The electrolyte is concentrated liquid phosphoric acid held in a porous silicon carbide matrix. Hydrogen ions carry the charge, as in a PEM cell.
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