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Plastics for the Future

Toxic gases from incinerating plastics

  • 3 things to know
  • AS 1

Overview

Carbon monoxide, hydrogen cyanide and hydrogen chloride from burning plastics, dioxins, open burning, flue gas cleaning and the 850°C two-second rule, the energy value of plastics, furniture fires and incineration as an option.

What you need to know

Answer each one before you reveal it.

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Key term

Name three toxic gases released when plastics are incinerated.

Key term

Why is carbon monoxide released when plastics burn?

Key term

Why is carbon monoxide from burning plastic so dangerous?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    Name three toxic gases released when plastics are incinerated.

    Model answer

    Three toxic gases are carbon monoxide, hydrogen cyanide and hydrogen chloride. Hydrogen chloride dissolves in moisture to form hydrochloric acid.

  2. 2

    Why is carbon monoxide released when plastics burn?

    Model answer

    Plastics are made mostly of carbon and hydrogen, and burning with too little oxygen causes incomplete combustion. Some of the carbon then forms carbon monoxide instead of carbon dioxide.

  3. 3

    Why is carbon monoxide from burning plastic so dangerous?

    Model answer

    Carbon monoxide binds to haemoglobin far more strongly than oxygen does, forming carboxyhaemoglobin. The blood then carries less oxygen, causing drowsiness, unconsciousness and death.

  4. 4

    Which plastics release hydrogen cyanide when they burn?

    Model answer

    Plastics that contain nitrogen release hydrogen cyanide as they burn. Examples are polyurethane foam, nylon and acrylonitrile-based plastics such as ABS.

  5. 5

    How does hydrogen cyanide harm the body?

    Model answer

    Hydrogen cyanide stops cells from using oxygen in aerobic respiration. A short exposure to a high concentration can kill within minutes.

  6. 6

    Which plastic is the main source of hydrochloric acid when plastic waste is burned?

    Model answer

    PVC is the main source, since every repeating unit carries a chlorine atom. The chlorine is released as hydrogen chloride gas, forming hydrochloric acid with moisture.

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