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Wave-Particle Duality

Calculations with the de Broglie equation

  • 3 things to know
  • Unit AS 2

Overview

Recall questions applying λ = h/mv to an electron, a proton, a neutron, a cricket ball and a walking person, working back from a wavelength to a speed or a momentum, the derivation of λ = h/√(2meV) for an accelerated electron, and why about 100 V is a suitable accelerating voltage for a demonstration.

What you need to know

Answer each one before you reveal it.

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Key term

At what speed must an electron travel to have a de Broglie wavelength of 1.0 × 10⁻¹⁰ m?

Key term

Derive an expression for the de Broglie wavelength of an electron accelerated from rest through a potential difference V.

Numbers

Calculate the de Broglie wavelength of an electron travelling at 1.0 × 10⁷ m s⁻¹.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    Calculate the de Broglie wavelength of an electron travelling at 1.0 × 10⁷ m s⁻¹.

    Model answer

    λ = h/mv = 6.63 × 10⁻³⁴ / (9.11 × 10⁻³¹ × 1.0 × 10⁷) = 7.3 × 10⁻¹¹ m, and 6.63 × 10⁻³⁴ ÷ 7.28 × 10⁻¹¹ returns a momentum of 9.11 × 10⁻²⁴ kg m s⁻¹ as required.

  2. 2

    An electron is accelerated from rest through a potential difference of 100 V. Calculate its de Broglie wavelength.

    Model answer

    Its kinetic energy is eV = 1.60 × 10⁻¹⁷ J, so v = √(2 × 1.60 × 10⁻¹⁷ / 9.11 × 10⁻³¹) = 5.93 × 10⁶ m s⁻¹ and λ = 6.63 × 10⁻³⁴ / (9.11 × 10⁻³¹ × 5.93 × 10⁶) = 1.2 × 10⁻¹⁰ m, and ½ × 9.11 × 10⁻³¹ × (5.93 × 10⁶)² returns 1.60 × 10⁻¹⁷ J.

  3. 3

    An electron is accelerated from rest through 2500 V. Calculate its de Broglie wavelength.

    Model answer

    Its kinetic energy is 1.60 × 10⁻¹⁹ × 2500 = 4.0 × 10⁻¹⁶ J, so v = √(2 × 4.0 × 10⁻¹⁶ / 9.11 × 10⁻³¹) = 2.96 × 10⁷ m s⁻¹ and λ = 6.63 × 10⁻³⁴ / (9.11 × 10⁻³¹ × 2.96 × 10⁷) = 2.5 × 10⁻¹¹ m, and ½ × 9.11 × 10⁻³¹ × (2.96 × 10⁷)² returns 4.0 × 10⁻¹⁶ J.

  4. 4

    Calculate the de Broglie wavelength of a proton travelling at 2.0 × 10⁶ m s⁻¹.

    Model answer

    λ = 6.63 × 10⁻³⁴ / (1.67 × 10⁻²⁷ × 2.0 × 10⁶) = 2.0 × 10⁻¹³ m, and 6.63 × 10⁻³⁴ ÷ 1.99 × 10⁻¹³ returns a momentum of 3.34 × 10⁻²¹ kg m s⁻¹.

  5. 5

    A neutron of mass 1.67 × 10⁻²⁷ kg moves at 3.0 × 10³ m s⁻¹. Calculate its de Broglie wavelength and comment on whether it could be diffracted by a crystal.

    Model answer

    λ = 6.63 × 10⁻³⁴ / (1.67 × 10⁻²⁷ × 3.0 × 10³) = 1.3 × 10⁻¹⁰ m, which is comparable with the spacing of atoms in a crystal, so such neutrons are diffracted strongly, and 6.63 × 10⁻³⁴ ÷ 1.32 × 10⁻¹⁰ returns a momentum of 5.0 × 10⁻²⁴ kg m s⁻¹.

  6. 6

    Calculate the de Broglie wavelength of a cricket ball of mass 0.16 kg moving at 30 m s⁻¹.

    Model answer

    λ = 6.63 × 10⁻³⁴ / (0.16 × 30) = 6.63 × 10⁻³⁴ / 4.8 = 1.4 × 10⁻³⁴ m, which is vastly smaller than an atomic nucleus, so no wave behaviour could ever be detected.

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