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Organic Chemistry

  • 10 subtopics
  • 30 things to know
  • A2 2

What Organic Chemistry covers

Organic Chemistry is examined in Unit A2 2, Organic Chemistry — examined, a core unit. It covers organic formulae, homologous series and functional groups, IUPAC naming and types of organic reaction, structural isomerism and E/Z isomerism, alkanes from crude oil, combustion and halogenation, vehicle pollutants, catalytic converters and biofuels, alkenes, pi bonds and electrophilic addition, classifying alcohols, making ethanol and its effects as a drug, oxidation of alcohols, IR spectroscopy and mass spectrometry, addition polymers, plastic waste and nylon and Preparing and purifying aspirin.

Where it is assessed

A2 2

Organic Chemistry — a written examination, compulsory.

Check the CCEA specification ↗

The 10 subtopics

Each one has its own page.

What you need to know

Answer each one before you reveal it.

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Key term

A hydrocarbon contains 85.7% carbon by mass and has a relative molecular mass of 56. What are its empirical and molecular formulae?

Key term

A compound contains 40.0% carbon, 6.7% hydrogen and 53.3% oxygen by mass, and its relative molecular mass is 180. What is its molecular formula?

Key term

How is crude oil separated by fractional distillation?

Process

Describe the free-radical mechanism for the chlorination of methane.

Key term

How does a catalytic converter reduce the harm caused by vehicle emissions?

Key term

Compare biofuels with fossil fuels as sources of energy for transport.

Process

Describe the electrophilic addition mechanism for the reaction of ethene with hydrogen bromide.

Key term

What are the IUPAC stems for carbon chains of one to six atoms?

Key term

What are structural isomers?

Key term

What is the general formula of the alcohols?

Key term

Write an equation for the dehydration of ethanol by concentrated phosphoric acid.

Key term

Why must a monomer contain a C=C double bond to form an addition polymer?

Key term

How is aspirin made in the laboratory?

Key term

How do suffixes show the functional group in an IUPAC name?

Key term

What are the three types of structural isomerism?

Key term

What is the general formula of the alkenes?

Key term

How are alcohols classified as primary, secondary or tertiary?

Key term

Which alkenes form when butan-2-ol is dehydrated?

Key term

Write an equation for the formation of poly(ethene) from ethene.

Key term

Write the equation for the synthesis of aspirin from salicylic acid.

Key term

What is a hydrocarbon?

Key term

What rules are followed when numbering a carbon chain in an IUPAC name?

Key term

Name the two structural isomers of C₄H₁₀.

Key term

What is the general formula of the alkanes?

Key term

Which pollutants form when alkane fuels burn in engines?

Key term

Why are alkenes described as unsaturated?

Key term

Classify butan-1-ol, butan-2-ol and 2-methylpropan-2-ol.

Key term

What oxidising agent is used to oxidise alcohols, and what colour change shows that a reaction has occurred?

Key term

Write an equation for the formation of poly(propene) from propene.

Key term

What type of reaction converts salicylic acid into aspirin?

Take Organic Chemistry further

The same content, four other ways.

Commonly confused

Pairs that lose marks when they are blurred together.

  • Empirical formula vs Molecular formula

    Empirical formula: the simplest whole-number ratio of atoms of each element in a compound. Molecular formula: the actual numbers of atoms of each element present, a whole-number multiple of the simplest ratio.

  • Sigma bond vs Pi bond

    Sigma bond: a covalent link formed by head-on overlap of orbitals between two nuclei. Pi bond: a covalent link formed by sideways overlap of p orbitals above and below the plane.

  • Addition polymerisation vs Condensation polymerisation

    Addition polymerisation: the joining of unsaturated monomers into a chain with no other product formed. Condensation polymerisation: the joining of monomers with two functional groups each, releasing a small molecule at every link.

Questions from this topic

Each one with the model answer underneath.

  1. 1

    What is a hydrocarbon?

    Model answer

    A hydrocarbon is a compound made of carbon and hydrogen atoms only. Methane, CH₄, and ethene, C₂H₄, are both hydrocarbons.

  2. 2

    What is the difference between an empirical formula and a molecular formula?

    Model answer

    An empirical formula gives the simplest whole-number ratio of atoms of each element in a compound. A molecular formula gives the actual number of atoms of each element in one molecule.

  3. 3

    How are the empirical and molecular formulae of a compound related?

    Model answer

    The molecular formula is a whole-number multiple of the empirical formula. The multiple is the relative molecular mass divided by the empirical formula mass.

  4. 4

    A hydrocarbon contains 85.7% carbon by mass and has a relative molecular mass of 56. What are its empirical and molecular formulae?

    Model answer

    The empirical formula is CH₂ and the molecular formula is C₄H₈. Hydrogen is 14.3%, and 85.7 ÷ 12 : 14.3 ÷ 1 = 7.14 : 14.3 = 1 : 2. The empirical mass is 14, and 56 ÷ 14 = 4.

  5. 5

    A compound contains 40.0% carbon, 6.7% hydrogen and 53.3% oxygen by mass, and its relative molecular mass is 180. What is its molecular formula?

    Model answer

    The molecular formula is C₆H₁₂O₆. Carbon gives 40.0 ÷ 12 = 3.33 mol and oxygen 53.3 ÷ 16 = 3.33 mol, against 6.7 mol of hydrogen. The 1 : 2 : 1 ratio gives CH₂O, of mass 30, and 180 ÷ 30 = 6.

  6. 6

    A sample of a hydrocarbon contains 2.4 g of carbon and 0.6 g of hydrogen, and its relative molecular mass is 30. What is its molecular formula?

    Model answer

    The molecular formula is C₂H₆. Carbon gives 2.4 ÷ 12 = 0.2 mol and hydrogen 0.6 ÷ 1 = 0.6 mol, a 1 : 3 ratio. The empirical formula CH₃ has mass 15, and 30 ÷ 15 = 2.

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Organic Chemistry revision questions

What does Organic Chemistry cover in CCEA A-Level Life and Health Sciences?
10 subtopics: organic formulae, homologous series and functional groups, iupac naming and types of organic reaction, structural isomerism and e/z isomerism, alkanes from crude oil, combustion and halogenation, vehicle pollutants, catalytic converters and biofuels, alkenes, pi bonds and electrophilic addition, classifying alcohols, making ethanol and its effects as a drug, oxidation of alcohols, ir spectroscopy and mass spectrometry, addition polymers, plastic waste and nylon and preparing and purifying aspirin. Each one has its own page with questions and model answers.
How is Organic Chemistry organised?
By the CCEA 0008 specification, subtopic by subtopic, so it matches the order you are taught it in.

Every question in Organic Chemistry, on a schedule.

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