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Plastics

Thermoplastics and thermosetting plastics

  • 3 things to know
  • AS 1 Paper 1

Overview

Polymers, thermoplastics and thermosets and their molecular structure, plastic memory, recycling and resin codes, stock forms, additives, and the advantages and drawbacks of plastics.

What you need to know

Answer each one before you reveal it.

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Key term

What is a polymer?

Key term

What is a thermoplastic?

Key term

Explain, in terms of molecular structure, why thermoplastics soften when heated.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What is a polymer?

    Model answer

    A polymer is a long-chain molecule made by joining many small monomer molecules together. Most plastics are synthetic polymers made from crude oil or natural gas.

  2. 2

    What is a thermoplastic?

    Model answer

    A thermoplastic is a polymer that softens when heated and can be reshaped many times. A thermoplastic hardens again on cooling without any chemical change.

  3. 3

    Explain, in terms of molecular structure, why thermoplastics soften when heated.

    Model answer

    Thermoplastic chains are held together by weak forces between the chains, with few or no cross-links. Heat overcomes these weak forces, so the chains slide past each other.

  4. 4

    What is a thermosetting plastic?

    Model answer

    A thermosetting plastic sets permanently when it is first heated or cured. A thermosetting plastic cannot be softened again and chars if strongly reheated.

  5. 5

    Explain why a thermosetting plastic does not soften when reheated.

    Model answer

    The curing reaction forms strong covalent cross-links between the polymer chains, locking them into a rigid network. The chains cannot slide, so the material stays rigid until it decomposes.

  6. 6

    Explain why thermosetting plastics tend to be more brittle than thermoplastics.

    Model answer

    Cross-links lock thermosetting chains rigidly, so they cannot slide to absorb energy. A thermosetting plastic therefore cracks rather than bends under a sharp blow.

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