Edexcel A-Level Chemistry 9CH0
Atomic Structure and the Periodic Table
Bonding and Structure
Inorganic Chemistry and the Periodic Table
Formulae, Equations and Amounts of Substance
Organic Chemistry I
Modern Analytical Techniques I
Energetics I
Kinetics I
Equilibrium I
Acid-Base Equilibria
Energetics II
Redox II
Transition Metals
Kinetics II
Organic Chemistry II
Organic Chemistry III
Acid-Base Equilibria
Buffer solutions and the Henderson-Hasselbalch equation
- 3 things to know
- Papers 1 and 3
Overview
Acidic and basic buffers and how an acidic buffer removes added H⁺ and OH⁻ ions, the Henderson–Hasselbalch equation, why pH equals pKₐ at half-equivalence so Kₐ can be read from a titration curve, and why a weak acid gives a less exothermic enthalpy of neutralisation.
What you need to know
Answer each one before you reveal it.
Define a buffer solution.
What components make up an acidic buffer?
Questions from this subtopic
Each one with the model answer underneath.
- 1
Define a buffer solution.
Model answer
A buffer solution is a solution that resists changes in pH when small amounts of acid or base are added.
- 2
What components make up an acidic buffer?
Model answer
A weak acid and its conjugate base (typically as a salt).
- 3
What components make up a basic buffer?
Model answer
A weak base and its conjugate acid (typically as a salt).
- 4
Explain how an acidic buffer responds when hydrogen ions are added.
Model answer
The conjugate base reacts with the added H⁺ ions to form the weak acid, removing the added hydrogen ions.
- 5
Explain how an acidic buffer responds when hydroxide ions are added to it.
Model answer
The added hydroxide ions react with the weak acid component of the buffer to form water and the conjugate base, thereby removing the added hydroxide ions and minimising pH change
- 6
What products are formed when hydroxide ions react with the weak acid in an acidic buffer solution?
Model answer
Water and the conjugate base of the weak acid
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