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Formulae, Equations and Amounts of Substance

Empirical formula and water of crystallisation by experiment

  • 3 things to know
  • Papers 1, 2 and 3

Overview

Finding an empirical formula by heating a substance in a crucible to constant mass, defining water of crystallisation, and finding x in a hydrated salt by heating, cooling and reweighing to constant mass and comparing the moles of anhydrous salt and water.

What you need to know

Answer each one before you reveal it.

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Key term

What is done to the substance in the crucible when determining empirical formula?

Key term

After achieving constant mass, how is the empirical formula determined?

Process

When determining empirical formula experimentally, what are the first two steps involving the crucible?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    When determining empirical formula experimentally, what are the first two steps involving the crucible?

    Model answer

    Weigh the crucible and lid, then add the substance and reweigh.

  2. 2

    What is done to the substance in the crucible when determining empirical formula?

    Model answer

    Heat strongly to complete the reaction.

  3. 3

    After heating the substance in the crucible, what must be done before reweighing?

    Model answer

    Cool the crucible and contents.

  4. 4

    Why is heating repeated when determining empirical formula experimentally?

    Model answer

    To ensure constant mass is achieved, indicating the reaction is complete.

  5. 5

    After achieving constant mass, how is the empirical formula determined?

    Model answer

    Calculate masses of each element, convert to moles, and determine the simplest whole number ratio.

  6. 6

    Define water of crystallisation.

    Model answer

    Water of crystallisation is water molecules incorporated into the crystal structure of a salt.

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