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Inorganic Chemistry and the Periodic Table

Flame tests and how they work

  • 2 things to know
  • Papers 1 and 3

Overview

How thermal energy promotes electrons in metal ions that emit light of characteristic wavelengths as they fall back, the flame colours of lithium, sodium, potassium, rubidium, caesium, calcium, strontium and barium compounds, and why magnesium compounds give no distinctive colour.

What you need to know

Answer each one before you reveal it.

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Key term

In a flame test, what is the initial energy source that causes electrons in metal ions to become excited?

Key term

Why is a flame test not useful for identifying magnesium compounds?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    In a flame test, what is the initial energy source that causes electrons in metal ions to become excited?

    Model answer

    Thermal energy from the flame

  2. 2

    When electrons in a metal ion absorb thermal energy during a flame test, what happens to their energy level?

    Model answer

    They are promoted to higher energy levels

  3. 3

    After excitation in a flame test, what do electrons do that results in light emission?

    Model answer

    They fall back to lower energy levels

  4. 4

    Why do different metal ions produce different flame colours?

    Model answer

    Because photons of characteristic wavelengths are emitted when excited electrons return to lower energy levels, and different metals have different energy level spacings

  5. 5

    What flame colour is produced by lithium compounds?

    Model answer

    Crimson/red

  6. 6

    What flame colour is produced by sodium compounds?

    Model answer

    Yellow/orange

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AAtomisation turns each element into gaseous atoms.
BIonisation energy removes electrons from the metal atoms.
CElectron affinity adds electrons to the non-metal atoms.

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