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Inorganic Chemistry and the Periodic Table

Disproportionation and the reactions of chlorine

  • 3 things to know
  • Papers 1 and 3

Overview

Recall questions on chlorine with cold and with hot alkali, on chlorine in water treatment, and on the oxidation number changes that make each a disproportionation.

What you need to know

Answer each one before you reveal it.

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Key term

Define disproportionation.

Key term

What products are formed when chlorine reacts with water?

Key term

Chlorine is bubbled into cold dilute sodium hydroxide — what comes out?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    Define disproportionation.

    Model answer

    A reaction where the same element is simultaneously oxidised and reduced.

  2. 2

    What products are formed when chlorine reacts with water?

    Model answer

    Chloride ions (in HCl) and chloric(I) acid (HClO).

  3. 3

    What is the oxidation state of chlorine in Cl₂?

    Model answer

    0.

  4. 4

    What is the oxidation state of chlorine in HCl, and what type of change is this from Cl₂?

    Model answer

    -1; this is a reduction.

  5. 5

    Why is chlorine used in water treatment?

    Model answer

    Because chloric(I) acid (HClO) formed when chlorine reacts with water kills bacteria.

  6. 6

    Chlorine is bubbled into cold dilute sodium hydroxide — what comes out?

    Model answer

    Sodium chloride (NaCl) and sodium chlorate(I) (NaClO), which is bleach.

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