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Redox I

  • 2 subtopics
  • 8 things to know
  • Papers 1, 2 and 3

What Redox I covers

Covers oxidation numbers and the rules for assigning them, the definitions of oxidation and reduction in terms of electrons, disproportionation, and building ionic equations from half-equations.

Where it is assessed

Papers 1, 2 and 3

Core inorganic and physical chemistry, drawn on by both context papers.

Check the Pearson Edexcel specification ↗

The 2 subtopics

Each one has its own page.

What you need to know

Answer each one before you reveal it.

Your recallNot started
Numbers

What are the standard rules for assigning oxidation numbers?

Process

How is a full ionic equation built from two half-equations?

Key term

What does a Roman numeral in a name tell you?

Numbers

In Cl₂ + H₂O ⇌ HCl + HClO, give the oxidation numbers of chlorine and explain why this is disproportionation.

Key term

What does an element's oxidation number mean?

Key term

Define oxidation in terms of electrons.

Key term

What is the oxidation number of a simple monatomic ion?

Key term

Define reduction in terms of electrons.

Take Redox I further

The same content, four other ways.

Commonly confused

Pairs that lose marks when they are blurred together.

  • Oxidation vs Reduction

    Oxidation: electron loss or an increase in oxidation number. Reduction: electron gain or a decrease in oxidation number.

  • Oxidising agent vs Reducing agent

    Oxidising agent: species accepting electrons. Reducing agent: species donating electrons.

  • Disproportionation vs Comproportionation

    Disproportionation: one species undergoing both electron loss and electron gain. Comproportionation: two assigned states forming one intermediate state.

Questions from this topic

Each one with the model answer underneath.

  1. 1

    What does an element's oxidation number mean?

    Model answer

    The charge an atom would have if all the bonds in the species were treated as fully ionic.

  2. 2

    What is the oxidation number of an atom in an uncombined element?

    Model answer

    Zero.

  3. 3

    What is the oxidation number of a simple monatomic ion?

    Model answer

    Equal to the charge on the ion (e.g. Na⁺ is +1, Cl⁻ is -1).

  4. 4

    What is the usual oxidation number of oxygen, and its exceptions?

    Model answer

    Usually -2; it is -1 in peroxides and +2 in the compound with fluorine (OF₂).

  5. 5

    What is the usual oxidation number of hydrogen, and its exception?

    Model answer

    Usually +1; it is -1 in metal hydrides such as NaH.

  6. 6

    What is the oxidation number of fluorine in its compounds?

    Model answer

    Always -1.

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Redox I
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AAtomisation turns each element into gaseous atoms.
BIonisation energy removes electrons from the metal atoms.
CElectron affinity adds electrons to the non-metal atoms.

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Anode means electrode where oxidation occurs.
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Redox I revision questions

What does Redox I cover in Edexcel A-Level Chemistry?
2 subtopics: oxidation numbers and oxidation, reduction, disproportionation and half-equations. Each one has its own page with questions and model answers.
How is Redox I organised?
By the Edexcel 9CH0 specification, subtopic by subtopic, so it matches the order you are taught it in.

Every question in Redox I, on a schedule.

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