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Organic Chemistry I

Alkenes, the double bond and hydrogenation

  • 3 things to know
  • Papers 2 and 3

Overview

Alkenes and cycloalkenes as unsaturated hydrocarbons, the σ-bond and π-bond in C=C and the orbital overlap that forms each, electrophiles, hydrogenation over a nickel catalyst and margarine manufacture, and the products of alkenes with halogens and with steam.

What you need to know

Answer each one before you reveal it.

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Key term

What conditions are required for the reaction of an alkene with steam, and what product is formed?

Key term

What two types of bond make up the carbon-carbon double bond in alkenes?

Key term

Where is the electron density of a π-bond located relative to the plane of an alkene molecule?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What is the general formula for alkenes?

    Model answer

    CₙH₂ₙ

  2. 2

    What type of hydrocarbons are cycloalkenes classified as?

    Model answer

    Unsaturated hydrocarbons.

  3. 3

    What two types of bond make up the carbon-carbon double bond in alkenes?

    Model answer

    One σ-bond and one π-bond.

  4. 4

    How is the σ-bond in an alkene formed?

    Model answer

    By end-on overlap of atomic orbitals along the internuclear axis.

  5. 5

    How is the π-bond in an alkene formed in terms of orbital overlap?

    Model answer

    By sideways overlap of p-orbitals

  6. 6

    Where is the electron density of a π-bond located relative to the plane of an alkene molecule?

    Model answer

    Above and below the plane of the molecule

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