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Inorganic Chemistry and the Periodic Table

Trends in Group 7 and predicting fluorine and astatine

  • 3 things to know
  • Papers 1 and 3

Overview

How London forces explain the melting and boiling temperatures and physical states of the halogens, the trends in atomic radius, shielding and electronegativity down Group 7, why reactivity decreases down the group, and predictions for fluorine and astatine covering their properties, displacement reactions, hydrogen halides and silver salts.

What you need to know

Answer each one before you reveal it.

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Key term

What trends run down group 7?

Key term

Why do the halogens require more energy to melt and boil as you descend the group?

Key term

How does the number of electrons change as you descend Group 7?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    How does the number of electrons change as you descend Group 7?

    Model answer

    The number of electrons increases down the group.

  2. 2

    What happens to the size of electron clouds in halogen molecules as you go down Group 7?

    Model answer

    Electron clouds become larger down the group.

  3. 3

    How does the strength of London dispersion forces between halogen molecules change down Group 7?

    Model answer

    London dispersion forces become stronger down the group.

  4. 4

    Why do the halogens require more energy to melt and boil as you descend the group?

    Model answer

    More energy is required to overcome the stronger intermolecular forces (London dispersion forces) between the larger molecules.

  5. 5

    What is the physical state of fluorine at room temperature?

    Model answer

    Gas.

  6. 6

    What is the physical state of chlorine at room temperature?

    Model answer

    Gas.

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