Edexcel A-Level Chemistry 9CH0
Atomic Structure and the Periodic Table
Bonding and Structure
Inorganic Chemistry and the Periodic Table
Formulae, Equations and Amounts of Substance
Organic Chemistry I
Modern Analytical Techniques I
Energetics I
Kinetics I
Equilibrium I
Acid-Base Equilibria
Energetics II
Redox II
Transition Metals
Kinetics II
Organic Chemistry II
Organic Chemistry III
Kinetics II
Determining orders from experiments
- 3 things to know
- Papers 2 and 3
Overview
The initial rate and continuous monitoring methods, deducing orders from initial rates, half-lives and rate-concentration graphs, techniques for following a rate, Core Practical 13a on the iodination of propanone, the iodine clock of Core Practical 13b, and finding k for a zero-order reaction.
What you need to know
Answer each one before you reveal it.
Using initial rates, how do you establish the order in one particular reagent?
What does half-life mean for a reaction?
Questions from this subtopic
Each one with the model answer underneath.
- 1
What is the initial-rate method?
Model answer
Run the reaction several times, varying one reagent's starting concentration and recording the initial rate for each run.
- 2
Using initial rates, how do you establish the order in one particular reagent?
Model answer
By seeing how the initial rate changes when the concentration of that reagent is changed, keeping others constant.
- 3
If doubling a reactant's concentration doubles the rate, what is the order with respect to it?
Model answer
First order.
- 4
If doubling a reactant's concentration quadruples the rate, what is the order with respect to it?
Model answer
Second order.
- 5
If changing a reactant's concentration has no effect on the rate, what is the order with respect to it?
Model answer
Zero order.
- 6
What is a continuous monitoring method?
Model answer
Following a single reaction over time to produce a concentration-time or volume-time graph.
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