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Bonding and Structure

  • 4 subtopics
  • 12 things to know
  • Papers 1, 2 and 3

What Bonding and Structure covers

Covers the three types of strong bonding, the shapes electron pair repulsion produces, electronegativity and the intermolecular forces that follow from it, and how the four structure types explain physical properties.

Where it is assessed

Papers 1, 2 and 3

Core inorganic and physical chemistry, drawn on by both context papers.

Check the Pearson Edexcel specification ↗

The 4 subtopics

Each one has its own page.

What you need to know

Answer each one before you reveal it.

Your recallNot started
Process

How does electron pair repulsion decide a molecule's shape?

Key term

What distinguishes the three kinds of intermolecular force?

Process

How does ionic radius affect the strength of ionic bonding?

Key term

Why does ionic radius decrease across the isoelectronic series from N³⁻ to Al³⁺?

Key term

Give two species that contain dative covalent bonding.

Key term

Define electronegativity.

Key term

What is graphene?

Key term

Why do simple molecular substances have low melting temperatures?

Key term

Define ionic bonding.

Key term

Define a covalent bond.

Key term

What are the two extremes of the bonding continuum?

Key term

Name the three types of giant lattice.

Take Bonding and Structure further

The same content, four other ways.

Commonly confused

Pairs that lose marks when they are blurred together.

  • Ionic bond vs Covalent bond

    Ionic bond: electrostatic attraction between oppositely charged ions. Covalent bond: attraction between shared electrons and both nuclei.

  • Bonding pair vs Lone pair

    Bonding pair: two shared electrons forming a covalent link. Lone pair: two outer-shell electrons not used in bonding.

  • Permanent dipole vs Instantaneous dipole

    Permanent dipole: lasting separation of partial charge. Instantaneous dipole: temporary separation caused by electron movement.

Questions from this topic

Each one with the model answer underneath.

  1. 1

    Define ionic bonding.

    Model answer

    Ions of opposite charge pulling strongly on one another.

  2. 2

    How does ionic charge affect the strength of ionic bonding?

    Model answer

    Greater ionic charge gives a stronger electrostatic attraction, so stronger ionic bonding.

  3. 3

    How does ionic radius affect the strength of ionic bonding?

    Model answer

    A smaller ionic radius gives stronger attraction, because the centres of charge are closer together.

  4. 4

    How are cations formed?

    Model answer

    By an atom losing one or more electrons.

  5. 5

    How are anions formed?

    Model answer

    By an atom gaining one or more electrons.

  6. 6

    How is a cation shown in a dot-and-cross diagram?

    Model answer

    In square brackets with its charge, usually with the outer shell empty because the electrons have been lost.

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Atomic Structure and the Periodic Table
Bonding and Structure
Redox I
Inorganic Chemistry and the Periodic Table

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AAtomisation turns each element into gaseous atoms.
BIonisation energy removes electrons from the metal atoms.
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Bonding and Structure revision questions

What does Bonding and Structure cover in Edexcel A-Level Chemistry?
4 subtopics: ionic bonding, covalent bonding, dative bonding and the shapes of molecules, electronegativity, polarity and intermolecular forces and structure and properties. Each one has its own page with questions and model answers.
How is Bonding and Structure organised?
By the Edexcel 9CH0 specification, subtopic by subtopic, so it matches the order you are taught it in.

Every question in Bonding and Structure, on a schedule.

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