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Energetics I

  • 2 subtopics
  • 6 things to know
  • Papers 1 and 3

What Energetics I covers

Covers the standard enthalpy definitions, measuring an enthalpy change by calorimetry, and calculating one from Hess cycles or from bond enthalpies.

Where it is assessed

Papers 1 and 3

Advanced Inorganic and Physical Chemistry, then the synoptic paper.

Check the Pearson Edexcel specification ↗

The 2 subtopics

Each one has its own page.

What you need to know

Answer each one before you reveal it.

Your recallNot started
Process

How does calorimetry measure an enthalpy change?

Key term

Why do bond enthalpy calculations only give an estimate?

Numbers

State the standard conditions used for enthalpy changes.

Key term

What physical state do bond enthalpy values assume?

Key term

What is an enthalpy change?

Key term

State Hess's law.

Take Energetics I further

The same content, four other ways.

Commonly confused

Pairs that lose marks when they are blurred together.

  • Exothermic change vs Endothermic change

    Exothermic change: process transferring heat from system to surroundings. Endothermic change: process transferring heat from surroundings to system.

  • Enthalpy of formation vs Enthalpy of combustion

    Enthalpy of formation: the enthalpy change when one mole of a compound forms from its elements. Enthalpy of combustion: the enthalpy change when one mole of a substance burns completely in oxygen.

  • Mean bond enthalpy vs Reaction enthalpy

    Mean bond enthalpy: average energy needed to break a specified gaseous covalent bond. Reaction enthalpy: heat change accompanying a reaction under stated conditions.

Questions from this topic

Each one with the model answer underneath.

  1. 1

    What is an enthalpy change?

    Model answer

    Heat taken in or given out while the pressure is held constant.

  2. 2

    State the standard conditions used for enthalpy changes.

    Model answer

    A pressure of 100 kPa and a stated temperature, usually 298 K.

  3. 3

    What is the sign of the enthalpy change for an exothermic reaction?

    Model answer

    Negative, because heat energy is released to the surroundings.

  4. 4

    What is the sign of the enthalpy change for an endothermic reaction?

    Model answer

    Positive, because heat energy is taken in from the surroundings.

  5. 5

    On an enthalpy level diagram, where are the products of an exothermic reaction relative to the reactants?

    Model answer

    Below the reactants, at lower enthalpy.

  6. 6

    On an enthalpy level diagram, where are the products of an endothermic reaction relative to the reactants?

    Model answer

    Above the reactants, at higher enthalpy.

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Atomic Structure and the Periodic Table
Bonding and Structure
Redox I
Inorganic Chemistry and the Periodic Table

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AAtomisation turns each element into gaseous atoms.
BIonisation energy removes electrons from the metal atoms.
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Energetics I revision questions

What does Energetics I cover in Edexcel A-Level Chemistry?
2 subtopics: enthalpy changes, standard definitions and calorimetry and hess's law and bond enthalpies. Each one has its own page with questions and model answers.
How is Energetics I organised?
By the Edexcel 9CH0 specification, subtopic by subtopic, so it matches the order you are taught it in.

Every question in Energetics I, on a schedule.

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