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Equilibrium II

Calculating Kp and the effect of conditions

  • 3 things to know
  • Papers 1 and 3

Overview

Finding equilibrium amounts to calculate Kc and Kp, working out their units, why only temperature changes the value of K and how it moves for exothermic and endothermic reactions, and what a large K says about the position of equilibrium.

What you need to know

Answer each one before you reveal it.

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Key term

Which conditions alter the value of an equilibrium constant?

Key term

What information is needed to calculate Kc from experimental data?

Key term

For an exothermic forward reaction, what happens to Kc or Kp when temperature is increased?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What information is needed to calculate Kc from experimental data?

    Model answer

    The equilibrium concentrations of all species that appear in the Kc expression.

  2. 2

    How are equilibrium amounts found from initial amounts and the amount reacted?

    Model answer

    By subtracting the amount reacted from initial reactants and adding the amount formed to products, using the balancing numbers.

  3. 3

    How are the units of an equilibrium constant found?

    Model answer

    By substituting the units of each term into the expression and cancelling.

  4. 4

    For an equilibrium with equal numbers of gas moles on both sides, what can be said about the units of Kp?

    Model answer

    They cancel, so Kp has no units.

  5. 5

    How is the total number of moles of gas used when calculating partial pressures?

    Model answer

    It is used to find each mole fraction before multiplying by the total pressure.

  6. 6

    Only one thing shifts the value of K — what?

    Model answer

    Temperature.

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