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Kinetics I

Collision theory and factors affecting rate

  • 3 things to know
  • Papers 2 and 3

Overview

The activation energy and correct orientation a successful collision needs, and how raising concentration, pressure and surface area increases the frequency of collisions rather than the proportion that succeed.

What you need to know

Answer each one before you reveal it.

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Process

What must be true for a collision to lead to reaction?

Key term

Why does increasing the pressure of a gaseous reaction increase the rate?

Key term

What must happen between particles for a reaction to occur?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What must happen between particles for a reaction to occur?

    Model answer

    Particles must collide with each other.

  2. 2

    Besides colliding, what two conditions must a collision satisfy to be successful?

    Model answer

    The particles must collide with energy equal to or greater than the activation energy and with the correct orientation.

  3. 3

    What does activation energy mean?

    Model answer

    The minimum energy that colliding particles must have for a reaction to take place.

  4. 4

    Why does increasing the concentration of a reactant increase the rate of reaction?

    Model answer

    There are more reactant particles in a given volume, so collisions are more frequent.

  5. 5

    Why does increasing the pressure of a gaseous reaction increase the rate?

    Model answer

    The gas particles are closer together in a smaller volume, so collisions are more frequent.

  6. 6

    Why does increasing the surface area of a solid reactant increase the rate?

    Model answer

    More reactant particles are exposed at the surface, so collisions with them are more frequent.

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BIonisation energy removes electrons from the metal atoms.
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