OCR A-Level Physics B H557
Planning
Implementing
Analysis
Evaluation
Practical Skills
Use of Apparatus and Techniques
Fundamental Data Analysis
Imaging and Signalling
Sensing
Mechanical Properties of Materials
Waves and Quantum Behaviour
Space, Time and Motion
Creating Models
Out Into Space
Our Place in the Universe
Matter: Very Simple
Matter: Hot or Cold
Electromagnetism
Charge and Field
Probing Deep Into Matter
Ionising Radiation and Risk
Matter: Hot or Cold
The Boltzmann factor and populations of energy states
- 3 things to know
- Components 01, 02 and 03
Overview
Recall questions on the Boltzmann factor e^(−E/kT) and why it is below one, its value when the step is kT or 10kT, calculating factors and populations, its limits at very high temperature and near absolute zero, why a small temperature rise matters so much, the classical approximation, finding an activation energy from rates, and states of equal energy.
What you need to know
Answer each one before you reveal it.
Why is the Boltzmann factor always less than one?
Calculate the Boltzmann factor when E/kT = 10.
Questions from this subtopic
Each one with the model answer underneath.
- 1
What is the Boltzmann factor?
Model answer
It is e^(−E/kT), the ratio of the number of particles in a state of energy E above another to the number in the lower state.
- 2
How does the ratio of the numbers of particles in two states depend on the energy difference between them?
Model answer
The ratio is e^(−ΔE/kT), so it falls exponentially as the energy gap widens.
- 3
Why is the Boltzmann factor always less than one?
Model answer
The exponent is negative, so fewer particles occupy the higher-energy state than the lower one.
- 4
What is the value of the Boltzmann factor when the energy step is exactly kT?
Model answer
It is e⁻¹, about 0.37.
- 5
Calculate the Boltzmann factor when E/kT = 10.
Model answer
The factor is e⁻¹⁰ = 4.5 × 10⁻⁵.
- 6
An energy step of 6.4 × 10⁻²⁰ J exists in a material at 290 K. Calculate the Boltzmann factor.
Model answer
kT = 4.0 × 10⁻²¹ J, so E/kT = 16 and the factor is e⁻¹⁶ = 1.1 × 10⁻⁷.
Other ways to work this
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