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Matter: Hot or Cold

The Boltzmann factor and populations of energy states

  • 3 things to know
  • Components 01, 02 and 03

Overview

Recall questions on the Boltzmann factor e^(−E/kT) and why it is below one, its value when the step is kT or 10kT, calculating factors and populations, its limits at very high temperature and near absolute zero, why a small temperature rise matters so much, the classical approximation, finding an activation energy from rates, and states of equal energy.

What you need to know

Answer each one before you reveal it.

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Key term

How does the ratio of the numbers of particles in two states depend on the energy difference between them?

Key term

Why is the Boltzmann factor always less than one?

Numbers

Calculate the Boltzmann factor when E/kT = 10.

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    What is the Boltzmann factor?

    Model answer

    It is e^(−E/kT), the ratio of the number of particles in a state of energy E above another to the number in the lower state.

  2. 2

    How does the ratio of the numbers of particles in two states depend on the energy difference between them?

    Model answer

    The ratio is e^(−ΔE/kT), so it falls exponentially as the energy gap widens.

  3. 3

    Why is the Boltzmann factor always less than one?

    Model answer

    The exponent is negative, so fewer particles occupy the higher-energy state than the lower one.

  4. 4

    What is the value of the Boltzmann factor when the energy step is exactly kT?

    Model answer

    It is e⁻¹, about 0.37.

  5. 5

    Calculate the Boltzmann factor when E/kT = 10.

    Model answer

    The factor is e⁻¹⁰ = 4.5 × 10⁻⁵.

  6. 6

    An energy step of 6.4 × 10⁻²⁰ J exists in a material at 290 K. Calculate the Boltzmann factor.

    Model answer

    kT = 4.0 × 10⁻²¹ J, so E/kT = 16 and the factor is e⁻¹⁶ = 1.1 × 10⁻⁷.

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