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Thermal Physics

Internal energy

  • 3 things to know
  • Component 1

Overview

Recall questions on the definition of internal energy as the sum of the random kinetic and potential energies of the particles, why it is a property of the state rather than of a process, what changes it, and how it differs for an ideal gas from a real one.

What you need to know

Answer each one before you reveal it.

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Key term

Define the internal energy of a system.

Key term

Which part of the internal energy of a substance depends on the separation of its molecules?

Key term

Which part of the internal energy of a substance depends on the temperature?

Questions from this subtopic

Each one with the model answer underneath.

  1. 1

    Define the internal energy of a system.

    Model answer

    The internal energy of a system is the sum of the random kinetic energies and the potential energies of all its molecules.

  2. 2

    Which part of the internal energy of a substance depends on the separation of its molecules?

    Model answer

    The potential energy contribution depends on the separation, because it arises from the forces the molecules exert on one another.

  3. 3

    Which part of the internal energy of a substance depends on the temperature?

    Model answer

    The random kinetic energy contribution depends on the temperature, since the mean molecular kinetic energy rises with the thermodynamic temperature.

  4. 4

    Why is the kinetic energy of a moving car not part of the internal energy of the car?

    Model answer

    Internal energy counts only the random motion of the molecules relative to the body, whereas the car's kinetic energy comes from the ordered motion of the whole body.

  5. 5

    Explain why melting a solid at its melting point increases the internal energy without changing the temperature.

    Model answer

    The energy supplied goes into separating the molecules against their mutual attraction, so the molecular potential energy rises while the mean kinetic energy, and therefore the temperature, stays the same.

  6. 6

    Explain why the internal energy of a real gas rises when it expands at constant temperature.

    Model answer

    The molecules move further apart against their weak mutual attractions, so their potential energy increases while their mean kinetic energy is unchanged.

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